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Showing 1–3 of 3 results
Advanced filters: Author: Jean-Yves Saillard Clear advanced filters

  • Understanding ligated metal clusters’ reactivities is challenging. Now, a methodology has been developed to explore dynamic mixtures of metal clusters. Interrelated cluster populations are constructed through organometallic precursor chemistry. Structural information on mixed-metal systems is obtained with a bias-free computational framework, and reactivities towards CO2 and alkynes are investigated in situ.

    • Raphael Bühler
    • Max Schütz
    • Roland A. Fischer
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 525-531

  • Atomically and structurally precise silver nanoclusters hold great potential for catalytic and optoelectronic applications. Here, the authors synthesize and characterize a series of atomically defined dithio- and diselenophosphate-protected eight-electron superatomic palladium-doped silver nanoclusters, including an unprecedented pair of selenolate-protected isomers.

    • Subrat Kumar Barik
    • Chih-Yuan Chen
    • C. W. Liu
    ResearchOpen Access
    Communications Chemistry
    Volume: 5, P: 1-12

  • Mixed-metal cluster generating reaction solutions contain several species of similar composition and structure that often result in hard-to-separate product mixtures. Here, the authors analyze elemental compositions obtained via high-resolution mass spectrometry with a computational permutative approach and assign individual structures of nickel gallium intermetalloid clusters without the need to isolate pure clusters.

    • Maximilian Muhr
    • Johannes Stephan
    • Roland A. Fischer
    ResearchOpen Access
    Communications Chemistry
    Volume: 7, P: 1-9