A series of free-standing poly(1,12-bis(carbazolyl)dodecane-co-3,4-ethylenedioxythiophene) (P(2Cz-D-co-EDOT)) films with crosslinking structure were synthesized electrochemically from 1,12-bis(carbazolyl)dodecane and 3,4-ethylenedioxythiophene. The obtained P(2Cz-D-co-EDOT) films show good redox activity and high electrochemical stability. Compared with those of poly(1,12-bis(carbazolyl)dodecane) and poly(3,4-ethylenedioxythiophene), the mechanical properties, electrical conductivities, thermoelectric properties and thermal stability of as-formed copolymer films are all improved in varying degrees.
- Ruirui Yue
- Baoyang Lu
- Congcong Liu