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Showing 1–8 of 8 results
Advanced filters: Author: Jinshuai Song Clear advanced filters
  • Reforming 3d-metal-based visible light catalytic platforms for inert bulk chemical activation is highly desirable. Herein, the authors report the use of a Brønsted acid to unlock robust and practical iron ligand-to-metal charge transfer photocatalysis for the activation of multifarious inert haloalkylcarboxylates to produce halogencontaining alkyl radicals.

    • Xiaoyu Jiang
    • Yu Lan
    • Linbin Niu
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-9
  • The direct hydroxylation of arene C–H bonds is a highly sought-after transformation but with little literature precedent. Herein the authors report a scalable electrochemical C–H hydroxylation of arenes in continuous flow for the synthesis of phenols.

    • Hao Long
    • Tian-Sheng Chen
    • Hai-Chao Xu
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-7
  • Oxidative allylic C–H functionalizations minimise the need for functional group activation and generate alkenyl-substituted products amenable to further chemical modifications. Here the authors report an oxidant-free, electrocatalytic approach to achieve intramolecular oxidative allylic C–H amination and alkylation by employing tailored cobalt-salen complexes as catalysts.

    • Chen-Yan Cai
    • Zheng-Jian Wu
    • Hai-Chao Xu
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-9
  • Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene migratory insertion-enabled 1,4-palladium shift.

    • Yinghua Yu
    • Pushkin Chakraborty
    • Xueliang Huang
    ResearchOpen Access
    Nature Communications
    Volume: 11, P: 1-9
  • Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP.

    • Qiang Ma
    • Jinshuai Song
    • Saihu Liao
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-8