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Showing 1–2 of 2 results
Advanced filters: Author: Jose A. Fernández-Salas Clear advanced filters

  • Benzothiophenes are common motifs in bioactive compounds, but selective functionalization at C3 is challenging. Here the authors report a method starting from benzothiophene S-oxides via an interrupted Pummerer reaction, giving access to a range of C3-alkylated and -arylated products.

    • Harry J. Shrives
    • José A. Fernández-Salas
    • David J. Procter
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-7

  • Although anion-binding processes are well-known for their crucial role in molecular recognition, this type of phenomenon has only recently been utilized for catalysis. Here, the authors present an enantioselective desymmetrization of cyclic keto sulfonium salts through enantioselective deprotonation/ring opening process by anion-binding catalysis.

    • José Alemán
    • Jorge Humbrías-Martín
    • Jose A. Fernández-Salas
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-11