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Showing 1–3 of 3 results
Advanced filters: Author: Kathiravan Murugesan Clear advanced filters

  • Synthesis of primary amines via operationally simple, inexpensive and environmentally friendly methodologies has high impact in industrial settings. Here, the authors show a reductive amination process involving a ruthenium catalyst, aldehydes/ketones, ammonia, and hydrogen that displays a remarkable scope of primary amine products.

    • Thirusangumurugan Senthamarai
    • Kathiravan Murugesan
    • Rajenahally V. Jagadeesh
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-12

  • Despite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen.

    • Kathiravan Murugesan
    • Zhihong Wei
    • Rajenahally V. Jagadeesh
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-9

  • Reductive amination is essential to the preparation of amines (e.g., pharmaceuticals and industrial products). This protocol shows how to prepare and use graphitic shell–encapsulated cobalt-based nanoparticles as catalysts for this reaction.

    • Kathiravan Murugesan
    • Vishwas G. Chandrashekhar
    • Matthias Beller
    Protocols
    Nature Protocols
    Volume: 15, P: 1313-1337