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Advanced filters: Author: Kennedy Ayoo Clear advanced filters

  • Magic-number Au11 clusters containing N-heterocyclic carbene (NHC) ligands are prepared by ligand exchange on known phosphine clusters and the introduction of even a single NHC results in improved cluster stability. The use of NHC-containing clusters in the electrocatalytic reduction of CO2 to CO is described and correlates with cluster stability.

    • Mina R. Narouz
    • Kimberly M. Osten
    • Cathleen M. Crudden
    Research
    Nature Chemistry
    Volume: 11, P: 419-425