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Showing 1–5 of 5 results
Advanced filters: Author: Kiminori Maeda Clear advanced filters
  • Animals of many kinds can orient themselves with respect to the Earth's magnetic field. Magnetic orientation seems to be through the eye, possibly by the magnetic modulation of a photochemical reaction. The problem is that nobody knows whether such modulation is even possible, for any chemical system, as that the Earth's magnetic field is relatively weak. This paper presents evidence that weak magnetic fields can modulate photochemical reactions in the expected manner. The model system is entirely artificial, and the temperature rather low, but the point has been made.

    • Kiminori Maeda
    • Kevin B. Henbest
    • P. J. Hore
    Research
    Nature
    Volume: 453, P: 387-390
  • The mechanism by which cryptochrome (CRY) proteins are capable of sensing weak magnetic fields (e.g., the geomagnetic field: ~50 μT) was suggested to be mediated by spin-correlated radical pairs (SCRPs) comprising a flavin adenine dinucleotide (FAD) radical and a tryptophan (Trp) radical which are formed simultaneously by light-induced electron transfer (ET). Here, the authors use time-resolved electron paramagnetic resonance (TREPR) spectroscopy to provide evidence for direct photoinduced ET responsible for the formation of long-lived SCRPs comprising a flavin (Fl) radical and a guanine (G) radical in flavin-tethered single- and double-stranded DNA oligomers.

    • Yoshimi Oka
    • Florian Quintes
    • Katsuya Inoue
    ResearchOpen Access
    Communications Chemistry
    Volume: 8, P: 1-8