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Showing 1–3 of 3 results
Advanced filters: Author: Maria Concistrè Clear advanced filters

  • Water molecules can exist in one of two nuclear spin states—ortho or para. Here, the authors look at the bulk dielectric constant of water molecules enclosed in fullerenes (capable of rotating even at cryogenic temperatures) and show that it changes as the water molecules convert from ortho to para.

    • Benno Meier
    • Salvatore Mamone
    • Malcolm H. Levitt
    ResearchOpen Access
    Nature Communications
    Volume: 6, P: 1-4

  • Hydrogen fluoride has been encapsulated in C60-fullerene using molecular surgery. The quantum rotor system has been studied by NMR and infrared spectroscopy as well as neutron scattering. The fullerene cage causes a small red-shift in the HF rotational and vibrational constants, and shields around 75% of its dipole.

    • Andrea Krachmalnicoff
    • Richard Bounds
    • Richard J. Whitby
    Research
    Nature Chemistry
    Volume: 8, P: 953-957