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Showing 1–2 of 2 results
Advanced filters: Author: Martin Gazvoda Clear advanced filters

  • Although the Sonogashira coupling of acetylenes and vinyl/aryl halides has been applied for decades, many mechanistic questions have remained unanswered. Here, the authors provide experimental and theoretical support for two interlinked palladium cycles operating in the debated Sonogashira coupling mechanism.

    • Martin Gazvoda
    • Miha Virant
    • Janez Košmrlj
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-9

  • Synergistic bimetallic catalysis has been proposed to be an alternative mechanism of palladium catalysed cross-coupling reactions, however, little is known about the details of this postulated dual catalysis. Here, the authors divide the mechanism of palladium catalysed cross-coupling of aryl halides and terminal alkynes into elementary steps and investigate the kinetics of each step independently.

    • Anže Ivančič
    • Janez Košmrlj
    • Martin Gazvoda
    ResearchOpen Access
    Communications Chemistry
    Volume: 6, P: 1-14