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Showing 1–3 of 3 results
Advanced filters: Author: Maurice van Gastel Clear advanced filters

  • Heavier analogues of unsaturated organic molecules are of interest because of their bonding situation and their potential use in synthesis. Now, a Bi(I)-based allyl cation, which can be seen as a heavy congener of all-carbon π-allyl cations, has been reported. This complex serves as a synthon for Bi(I) transfer, enabling access to low-valent organobismuth compounds.

    • Davide Spinnato
    • Nils Nöthling
    • Josep Cornella
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 265-270

  • Understanding the catalytic mechanism of redox-active hydrogenases is a key to efficient hydrogen production and consumption. Here, the authors use nuclear resonance vibrational spectroscopy to study [NiFe]-hydrogenase, and observe a bridging hydride structure in an EPR silent intermediate.

    • Hideaki Ogata
    • Tobias Krämer
    • Stephen P. Cramer
    ResearchOpen Access
    Nature Communications
    Volume: 6, P: 1-8