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Showing 1–6 of 6 results
Advanced filters: Author: Michael Mastalerz Clear advanced filters

  • Organic molecular crystals with guest-occupied cavities are often observed, but the cavities tend to collapse when the guests are removed. Now, the porous domain of a crystalline solvate has been stabilized by formation of a cocrystal with a second molecule whose size and shape matches those of the unstable voids.

    • Marc A. Little
    • Michael E. Briggs
    • Andrew I. Cooper
    Research
    Nature Chemistry
    Volume: 7, P: 153-159

  • Millimetre-sized single crystals of covalent organic frameworks have been constructed by taking advantage of a reversible dimerization reaction of nitroso groups.

    • Michael Mastalerz
    News & Views
    Nature Chemistry
    Volume: 5, P: 810-811

  • Porous solids have many uses in the chemical industry, which has stimulated the development of several generations of such materials. A new generation has now arrived, with the report of permanently porous liquids. See Letter p.216

    • Michael Mastalerz
    News & Views
    Nature
    Volume: 527, P: 174-175

  • Interlocked shape-persistent organic cages are rare structures and the majority are formed using π-stacking as the driving force. Now it is shown that weak dispersion interactions—which are modulated by changing the 1,4-substituents of the constituent dialdehyde linkers—can be used to form interlocked dimeric and trimeric catenated cages.

    • Bahiru Punja Benke
    • Tobias Kirschbaum
    • Michael Mastalerz
    ResearchOpen Access
    Nature Chemistry
    Volume: 15, P: 413-423

  • The separation of multicomponent mixtures is performed by distillation, as multiple-membrane cascades are too complex. Here, a porous organic cage composite undergoes solid-state transformation in solvent; this alters pore size, enabling graded separation of three dyes with a single membrane.

    • Ai He
    • Zhiwei Jiang
    • Andrew I. Cooper
    ResearchOpen Access
    Nature Materials
    Volume: 21, P: 463-470