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Showing 1–5 of 5 results
Advanced filters: Author: Michael Mingos Clear advanced filters

  • In comparison to their neutral or anionic counterparts, examples of cationic boron clusters remain scarce. Here, the authors prepare a variety of cationic polyhedral boranes by reacting closo-10-vertex carboranes with N-heterocyclic carbenes; the resulting open-cage cationic nido- arachno- or closo- derivatives are water soluble, which may enable unprecedented applications.

    • Jan Vrána
    • Josef Holub
    • Aleš Růžička
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-7

  • Dimetallocenes are a narrow class of compounds represented by the homobimetallic examples dizincocene and diberyllocene. Now a heterobimetallic dimetallocene featuring lithium and aluminium centres has been synthesized. The Al–Li bond is shown to cleave upon reaction with N-heterocyclic carbenes and heteroallenes.

    • Inga-Alexandra Bischoff
    • Sergi Danés
    • André Schäfer
    ResearchOpen Access
    Nature Chemistry
    Volume: 16, P: 1093-1100