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Showing 1–2 of 2 results
Advanced filters: Author: Michael Morasch Clear advanced filters
  • Following the building principles of crown ethers for cation encapsulation, inverse crowns are rings of metals that bind anions. Now a redox-active inverse crown ether featuring Na+ cations and Mg0 has been shown to reduce epoxides, N2O, S8 or O2 by combining anion complexation by the ring of metal cations with the reducing power of Mg0.

    • Johannes Maurer
    • Lukas Klerner
    • Sjoerd Harder
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 703-709
  • Proton motive forces are central for life but it is not well understood how these pH gradients emerged at the beginning of life. Here the authors show that heat flow across a water-filled chamber forms and sustains stable pH gradients and support their experimental findings with simulations.

    • Lorenz M. R. Keil
    • Friederike M. Möller
    • Christof B. Mast
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-9