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Advanced filters: Author: Nai-Tzu Kuo Clear advanced filters

  • The amorphous phase and crystalline morphology of the poly(vinyl methyl ether) (PVME)/poly(1,6-hexamethylene adipate) (PHA) blend were compared with those of the classical PVME/poly(ɛ-caprolactone) (PCL) system, isomeric to the former. Both blend systems’ amorphous phases are similarly miscible with χ12=−0.2. In contrast, the crystalline phases of these two blends differ significantly. When crystallized at high Tc (46 °C or above), the PVME/PCL (20/80) blend assumes fluffy feather-like dendrites (Graph-a), which are dramatically different from straight-stalk dendrites in the PVME/PHA (20/80) blend (Graph-b).

    • Eamor M Woo
    • Ying-Hsuan Chou
    • Nai-Tzu Kuo
    Research
    Polymer Journal
    Volume: 42, P: 391-400