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Showing 1–3 of 3 results
Advanced filters: Author: Nathan J. Yutronkie Clear advanced filters

  • Phosphorus mononitride is highly unstable under atmospheric conditions and its utility for constructing elusive P–N π-bonded motifs has remained uncertain. Here, the authors show that Na(OCP) can transfer a P atom to an electrophilic osmium nitride complex to form a metal-bound P≡N ligand.

    • Simon Edin
    • Christian Sandoval-Pauker
    • Anders Reinholdt
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-12

  • Valence tautomerism in lanthanide-based materials is rare. Now a one-dimensional samarium–pyrazine polymer has been shown to exhibit a temperature-induced hysteretic Sm(III)-to-Sm(II) reversible switch. The transition temperature is modulated in a 150 K window by alloying with Yb(II), presenting a strategy for developing new materials with chemically tunable magnetic switchability.

    • Maja A. Dunstan
    • Anna S. Manvell
    • Kasper S. Pedersen
    Research
    Nature Chemistry
    Volume: 16, P: 735-740

  • Ultrasmall metallic clusters receive great attention for atom-efficient catalysts. Here a metallic cluster–organic framework is synthesized and characterized; authors demonstrate its stability and catalytic proficiency, paving the way for molecular-scale metal nanoparticle interlocking.

    • Xiyue Liu
    • James N. McPherson
    • Kasper S. Pedersen
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-10