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Showing 1–2 of 2 results
Advanced filters: Author: Nency P. Domingues Clear advanced filters

  • Here authors investigate the effects of different metals incorporated in the structures and possible additional phases have on the CO2 uptake of pyrene-based MOFs. Results show that when additional phases are present, the pore volume is reduced and CO2 binding sites in the structure are different, leading to different adsorption properties.

    • Nency P. Domingues
    • Miriam J. Pougin
    • Berend Smit
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-12

  • Metal-organic frameworks with desirable properties can be designed through careful choice of linker and node combinations, but achieving the synthesis of a desired MOF is complex and dependent on many experimental variables. Here, a genetic algorithm combined with experimental feedback and confirmation is used to obtain the optimal microwave-assisted synthesis conditions for a porphyrin-based aluminium MOF (Al-PMOF), achieving excellent crystallinity and a close to 80% yield in only the 2nd generation.

    • Nency P. Domingues
    • Seyed Mohamad Moosavi
    • Berend Smit
    ResearchOpen Access
    Communications Chemistry
    Volume: 5, P: 1-8