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Showing 1–3 of 3 results
Advanced filters: Author: Nils Nöthling Clear advanced filters
  • Heavier analogues of unsaturated organic molecules are of interest because of their bonding situation and their potential use in synthesis. Now, a Bi(I)-based allyl cation, which can be seen as a heavy congener of all-carbon π-allyl cations, has been reported. This complex serves as a synthon for Bi(I) transfer, enabling access to low-valent organobismuth compounds.

    • Davide Spinnato
    • Nils Nöthling
    • Josep Cornella
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 265-270
  • Nickel complexes are of ever-increasing importance in organic synthesis; however, unstable Ni(COD)2 is still the main Ni(0) source used. Here the authors report a solution to this long-standing issue: an air stable Ni(0) complex that acts as a general precatalyst for numerous nickel-catalysed reactions.

    • Lukas Nattmann
    • Rakan Saeb
    • Josep Cornella
    Research
    Nature Catalysis
    Volume: 3, P: 6-13