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Showing 1–2 of 2 results
Advanced filters: Author: Pannan Miao Clear advanced filters

  • The selective cleavage of inert C(sp3)-C(sp3) bonds and their subsequent functionalization is an important goal in synthetic organic chemistry. Here, the authors developed consecutive C–C bond cleavage from stable trisubstituted acids via photocatalysis and copper catalysis.

    • Ruining Li
    • Ya Dong
    • Zhankui Sun
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-12

  • Due to the ionic nature of its mechanism, the Mannich reaction can only use non-enolizable aldehydes as substrates. Here, the authors expand the scope of the classical Mannich reaction to enolizable aldehydes by employing a radical process resulting in a streamlined synthesis of γ-amino-carbonyl compounds.

    • Shuai Shi
    • Wenting Qiu
    • Zhankui Sun
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-7