Nature Search

Construction of C-B axial chirality via dynamic kinetic asymmetric cross-coupling mediated by tetracoordinate boron

The application of catalytic dynamic kinetic asymmetric transformation (DyKAT) in axial chirality is limited to fivemembered metalacyclic intermediate-directed equilibrium of substrate enantiomers. Here, the authors report a tetracoordinate boron-directed DyKAT of racemic, configurationally stable 3-bromo- 2,1-azaborines for the construction of C-B axial chirality.

Kai Yang
Yanfei Mao
Qiuling Song
ResearchOpen Access24 Jul 2023
Nature Communications

Volume: 14, P: 1-10
Identifying a highly efficient molecular photocatalytic CO₂ reduction system via descriptor-based high-throughput screening

High-throughput computational screening of multicomponent molecular photocatalytic systems offers a strategy to minimize the screening of large numbers of photosensitizer–catalyst combinations. Here a machine learning-accelerated approach using multiple descriptors shows strong predictive power in experimentally validated systems for CO₂ reduction.

Yangguang Hu
Can Yu
Yujie Xiong
Research07 Feb 2025
Nature Catalysis

Volume: 8, P: 126-136
Unusual Li₂O sublimation promotes single-crystal growth and sintering

Single-crystal Ni-rich cathode materials are highly sought after in battery development. In this study the authors present a synthesis route that leverages Li₂O sublimation to facilitate the production of high-performance single-crystal cathode materials.

Bingbin Wu
Ran Yi
Jie Xiao
ResearchOpen Access06 Mar 2025
Nature Energy

Volume: 10, P: 605-615
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes

Axial chirality is a key element in many valuable compounds, such as ligands in organic chemistry or pharmaceuticals. Now the catalytic atroposelective synthesis of acyclic 1,3-dienes by chiral phosphoric acid-catalysed bromination is described, expanding the chemical space of axially chiral compounds.

Quan-Hao Wu
Meng Duan
Bin Tan
Research17 Jan 2024
Nature Catalysis

Volume: 7, P: 185-194
Direct in situ measurements of electrical properties of solid–electrolyte interphase on lithium metal anodes

The solid–electrolyte interphase is widely viewed as key to governing the performance of rechargeable batteries, but its electrical properties remain elusive. Here the authors develop an experimental approach to directly measure the properties and show that the solid–electrolyte interphase has a voltage-dependent conducting behaviour.

Yaobin Xu
Hao Jia
Chongmin Wang
Research28 Sept 2023
Nature Energy

Volume: 8, P: 1345-1354
Peripheral blood circular RNA hsa_circ_0124644 can be used as a diagnostic biomarker of coronary artery disease

Zhenzhou Zhao
Xuejie Li
Muwei Li
ResearchOpen Access03 Jan 2017
Scientific Reports

Volume: 7, P: 1-9
Synchronous detection of dual signals based on constant-drive technique of weakly coupled resonators

Han Li
Zhao Zhang
Honglong Chang
ResearchOpen Access09 May 2025
Microsystems & Nanoengineering

Volume: 11, P: 1-13
Integrative metagenomic and metabolomic analyses reveal the potential of gut microbiota to exacerbate acute pancreatitis

Jianjun Liu
Qiulong Yan
Dong Shang
ResearchOpen Access21 Mar 2024
npj Biofilms and Microbiomes

Volume: 10, P: 1-14
In situ XRD and operando spectra-electrochemical investigation of tetragonal WO_3-x nanowire networks for electrochromic supercapacitors

The synchronous correspondence relationship between the optical and charge storage performances, and the synergistic intrinsic mechanism between the Al³⁺ ion intercalation and the surface pseudocapacitance reaction affecting the electrochromic-energy storage performance are revealed using in-situ/operando techniques.

Shen Wang
Hongbo Xu
Yao Li
ResearchOpen Access09 Jul 2021
NPG Asia Materials

Volume: 13, P: 1-11

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