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Showing 1–4 of 4 results
Advanced filters: Author: Qixue Qin Clear advanced filters

  • The direct oxygenation of C–C bonds through single-oxygen-atom insertion like the Baeyer-Villiger reaction is of particular significance. Herein, the authors present an approach for the skeletal modification of styrene using O2 via oxygen insertion, resulting in the formation of aryl ether frameworks under mild reaction conditions.

    • Qixue Qin
    • Liang Zhang
    • Ning Jiao
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-7

  • Aliphatic alcohols usually require pre-activation for successful functionalization of their carbon chain. Here, the authors report a silver-catalyzed δ-selective functionalization of aliphatic alcohols via Csp3-H bond cleavage under mild conditions without the need of substrate pre-activation.

    • Yuchao Zhu
    • Kaimeng Huang
    • Ning Jiao
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-7

  • Limitations associated with the primary amination of aryl C–H bonds include the poor control of regioselectivity with electron-rich substrates and the challenging nature of the reaction in the case of electron-deficient arenes. Now, site-directed C–C bond primary amination of simple alkylarenes and benzyl alcohols provides a route for the direct and efficient preparation of anilines.

    • Jianzhong Liu
    • Xu Qiu
    • Ning Jiao
    Research
    Nature Chemistry
    Volume: 11, P: 71-77