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Showing 1–5 of 5 results
Advanced filters: Author: Rebecca Musgrave Clear advanced filters
  • A new class of organometallic compound has been made that has a distinctive geometry and electronic structure — with potential for catalysis and materials science.

    • Rebecca Musgrave
    News & Views
    Nature
    Volume: 641, P: 43-44
  • Chemists have long been fascinated by electron delocalization, from both a fundamental and applied perspective. Macrocyclic oligomers containing fused ferrocenes provide a new structural framework — containing strongly interacting metal centres — that is capable of supporting substantial charge delocalization.

    • Rebecca A. Musgrave
    • Ian Manners
    News & Views
    Nature Chemistry
    Volume: 8, P: 819-820
  • Main-chain polymetallocenes are typically static in nature due to strong metal–ligand bonding. Now, it has been shown that such polymers based on nickelocene are dynamic due to weaker nickel–cyclopentadienyl interactions, and at low concentration or at elevated temperature, depolymerization to the moderately strained monomer occurs.

    • Rebecca A. Musgrave
    • Andrew D. Russell
    • Ian Manners
    Research
    Nature Chemistry
    Volume: 9, P: 743-750