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Cooperative Cu/azodiformate system-catalyzed allylic C–H amination of unactivated internal alkenes directed by aminoquinoline

The oxidative intermolecular amination of C-H bonds represents a straightforward method to construct aliphatic allylic amines. However, the utilization of widely available internal alkenes remains a synthetic challenge. Here, the authors present a regioselective Cu-catalyzed oxidative allylic C-H amination of internal olefins with azodiformates.

Le Wang
Cheng-Long Wang
Shu-Yu Zhang
ResearchOpen Access19 Feb 2024
Nature Communications

Volume: 15, P: 1-10
Astragaloside IV inhibits spontaneous synaptic transmission and synchronized Ca²⁺ oscillations on hippocampal neurons

Shao-qing Zhu
Lei Qi
Zuo-ping Xie
Research01 Jan 2008
Acta Pharmacologica Sinica

Volume: 29, P: 57-64
Megaelectronvolt electron acceleration driven by terahertz surface waves

When near-infrared femtosecond laser pulses are focused onto a metal wire, relativistic electron acceleration is observed in the attached waveguide. An electron energy gain of 1.1 MeV and an effective acceleration gradient up to 210 MV m⁻¹ are achieved using the laser-induced terahertz surface waves.

Xie-Qiu Yu
Yu-Shan Zeng
Ru-Xin Li
Research13 Jul 2023
Nature Photonics

Volume: 17, P: 957-963

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