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Showing 1–3 of 3 results
Advanced filters: Author: Samuel O. Odoh Clear advanced filters

  • The oxo groups in the common trans-uranyl ion — present in the majority of known uranium compounds — are linear and inert. Now, a new reduced binuclear uranium–dioxo compound with very strong metal coupling and remarkable air stability has been formed through oxo migration and silylation.

    • Polly L. Arnold
    • Guy M. Jones
    • Jason B. Love
    Research
    Nature Chemistry
    Volume: 4, P: 221-227

  • Multi-electron redox chemistry is important in transition-metal-mediated processes, but is rarely observed with uranium due to its propensity to undergo single-electron reactions. Now, uranium can use its electrons, coupled with those stored in redox-active ligands, to perform multi electron reduction of organoazides and form uranium tris(imido) derivatives.

    • Nickolas H. Anderson
    • Samuel O. Odoh
    • Suzanne C. Bart
    Research
    Nature Chemistry
    Volume: 6, P: 919-926