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Showing 1–2 of 2 results
Advanced filters: Author: Satoshi Inayama Clear advanced filters

  • Zinc diacrylate (ZDA) gave the polymer as shown in the scheme by heating in the solid state. When additives like diphenyl disulfide (DPDS), thiophenol (TP) and dicumyl peroxide (DCP) were mixed in 1/60 molar ratio to ZDA, qualitative order of the polymerization rate was obtained to be ZDA < ZDA-DPDS(or TP) << ZDA-DPDS(or TP)-DCP < ZDA-DCP. Namely, mixing these additives to ZDA accelerated the solid-state polymerization.

    • Junki Tsuchida
    • Yosuke Saito
    • Mikio Yamada
    Research
    Polymer Journal
    Volume: 45, P: 1007-1012

  • 10,12,14,16,18,20-Triacontahexayne-1,30-diol and its diphenylurethane and diphenylester were synthesized, and their solid-state polymerization behaviors were investigated. The regular two-step solid-state polymerization was confirmed for the diphenylurethane derivative.

    • Satoshi Inayama
    • Yoko Tatewaki
    • Shuji Okada
    Research
    Polymer Journal
    Volume: 42, P: 201-207