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Showing 1–2 of 2 results
Advanced filters: Author: Sergey N. Maximoff Clear advanced filters

  • Interactions between nano-porous materials and gases possess rich redox chemistry. Here, the authors report a metal organic framework, a nano-porous material, that undergoes an atypical metal–insulator–metal transition intertwined with oxygen adsorption-desorption, which defies the classical picture.

    • Sergey N. Maximoff
    • Berend Smit
    Research
    Nature Communications
    Volume: 5, P: 1-9

  • Metal–organic frameworks featuring unsaturated metal sites have emerged as promising materials for CO2 capture, but the host–guest interactions at play have remained poorly understood. An approach based on quantum chemical calculations has now been devised to generate force fields that accurately describe a MOF's metal sites and predict its gas uptake abilities.

    • Allison L. Dzubak
    • Li-Chiang Lin
    • Laura Gagliardi
    Research
    Nature Chemistry
    Volume: 4, P: 810-816