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Showing 1–4 of 4 results
Advanced filters: Author: Stephen A. Moggach Clear advanced filters

  • While thermally- and photo-induced valence tautomerism, which is stimulated intramolecular electron transfer between a metal and coordinated redox-active ligand, has been explored extensively, less is known about pressure-induced valence tautomerism. Here, the authors report pressure-triggered valence tautomerism in a thermally inactive cobalt complex.

    • Aston Summers
    • F. Zahra M. Zahir
    • Stephen A. Moggach
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-9

  • Porous molecular crystals are easy to fabricate but thought to have limited stability as they are bound by non-covalent interactions. Here, a porous crystal composed of C60 and phthalocyanine is demonstrated with stability to heat, acid, base and high pressures.

    • C. Grazia Bezzu
    • Luke A. Burt
    • Neil B. McKeown
    Research
    Nature Materials
    Volume: 18, P: 740-745

  • Understanding host–guest interactions and structural changes within porous materials is crucial for enhancing gas storage properties. Here, the authors combine cryogenic loading of gases with high pressure crystallography and computational techniques to obtain atomistic detail of adsorption-induced structural and energetic changes in ZIF-8.

    • Claire L. Hobday
    • Christopher H. Woodall
    • Stephen A. Moggach
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-9

  • Materials that demonstrate long-range magnetic order are synonymous with information storage. Here, the authors report the effect of pressure on two mononuclear rhenium compounds that exhibit long-range magnetic order under ambient conditions via a spin canting mechanism, whereTcis proportional to pressure.

    • Christopher H. Woodall
    • Gavin A. Craig
    • Euan K. Brechin
    ResearchOpen Access
    Nature Communications
    Volume: 7, P: 1-7