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Showing 1–2 of 2 results
Advanced filters: Author: Susannah Coote Clear advanced filters

  • The synthesis of 1,3- and 1,2-disubstituted cubanes is achieved using a cyclobutadiene precursor and a photolytic carboxylation reaction, respectively, and copper-catalysed amination, arylation, alkylation and trifluoromethylation reactions have been developed enabling the use of cubanes as bioisosteres of benzenes in drug design.

    • Mario P. Wiesenfeldt
    • James A. Rossi-Ashton
    • David W. C. MacMillan
    Research
    Nature
    Volume: 618, P: 513-518

  • The [2+2] photocycloaddition of two double-bond moieties is arguably the most efficient way to form a four-membered ring, but this route is rarely used to construct azetidine rings. Now, the development of an isoxazoline carboxylate cycloaddition partner offers a general approach to synthesize diverse azetidine products.

    • Susannah Coote
    News & Views
    Nature Chemistry
    Volume: 12, P: 889-890