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Advanced filters: Author: Tristan Maschmeyer Clear advanced filters

  • The Suzuki-Miyaura coupling (SMC) is widely used in C-C bond forming reactions but the dominant mode of transmetalation remains controversial. Here the authors report a mechanistic study of a Pd catalyzed SMC under biphasic conditions where using phase transfer catalysts shifts the dominant mode of transmetalation resulting in rate enhancement.

    • Yao Shi
    • Joshua S. Derasp
    • Jason E. Hein
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-12