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Showing 1–4 of 4 results
Advanced filters: Author: Tristan von Münchow Clear advanced filters
  • Controlling the selectivity of electrocatalysed C–H activation with earth-abundant base metals can increase its synthetic impact. Now chemodivergence of an electrocatalysed enantioselective C–H activation is achieved by using either ligand-bound Ni or Co in the catalytic system.

    • Tristan von Münchow
    • Neeraj Kumar Pandit
    • Lutz Ackermann
    ResearchOpen Access
    Nature Catalysis
    Volume: 8, P: 257-269
  • Traditional methylamine synthesis from methanol and ammonia relies on high-temperature and high-pressure reaction conditions, resulting in byproducts and challenging purification. Now, electrochemical nitromethane reduction under mild conditions has been realized with a copper catalyst, enabling selective and sustainable methylamine synthesis.

    • Tristan von Münchow
    • Lutz Ackermann
    News & Views
    Nature Chemistry
    Volume: 17, P: 1144-1145
  • Enantioselective electrocatalysis is emerging as an increasingly versatile tool in organic synthesis. Now, by applying asymmetric Lewis acid catalysis with an elaborated ligand design, radical electrochemical amination is accomplished with full selectivity control.

    • Tristan von Münchow
    • Lutz Ackermann
    News & Views
    Nature Synthesis
    Volume: 2, P: 1132-1133
  • C–H activation in organic chemistry usually relies on precious and toxic transition metals. Now it is reported that a sustainable photo-promoted iron-catalysed aromatic imine C–H alkenylation reaction with alkynes circumvents previous limitations of related iron-catalysed reactions that required additives or high reaction temperatures.

    • Antonis M. Messinis
    • Tristan von Münchow
    • Lutz Ackermann
    Research
    Nature Catalysis
    Volume: 7, P: 273-284