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Showing 1–2 of 2 results
Advanced filters: Author: V. Nicholas Vukotic Clear advanced filters

  • The dynamics of mechanically interlocked molecules such as catenanes and rotaxanes have been studied in solution as examples of rudimentary molecular switches and machines. A metal–organic framework with a [2]rotaxane as a building block demonstrates that such dynamic processes can also operate inside a solid-state material.

    • V. Nicholas Vukotic
    • Kristopher J. Harris
    • Stephen J. Loeb
    Research
    Nature Chemistry
    Volume: 4, P: 456-460

  • The piston-like, translational motion of a molecular shuttle — a process that is fundamental to many mechanically interlocked molecular switches and machines — has now been demonstrated to occur inside the highly organized and dense structure (containing approximately 1021 shuttles per cm3) of a metal–organic framework material.

    • Kelong Zhu
    • Christopher A. O'Keefe
    • Stephen J. Loeb
    Research
    Nature Chemistry
    Volume: 7, P: 514-519