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Showing 1–3 of 3 results
Advanced filters: Author: Vinod G. Landge Clear advanced filters

  • C-H activation reactions allow transformations on relatively unfunctionalised organic molecules. Here, the authors describe rhodium-catalysed C-H bond activation of unprotected anilines with alkynes leading to C-C bond formation (rather than the more usual C-N), and subsequent annulation to form quinolines.

    • Siba P. Midya
    • Manoj K. Sahoo
    • Ekambaram Balaraman
    ResearchOpen Access
    Nature Communications
    Volume: 6, P: 1-10

  • Catalytic acceptorless dehydrogenation reactions provide a sustainable route to valuable products and hydrogen fuel. Here, the authors show a recyclable iron catalyst that is highly active in the acceptorless dehydrogenation of a wide range of N-heterocycles and alcohols.

    • Garima Jaiswal
    • Vinod G. Landge
    • Ekambaram Balaraman
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-13

  • Tertiary amines are poor directing groups for C(sp3)–H activation using Pdii catalysts due to favourable β-hydride elimination pathways. Now, an N-acetyl amino acid ligand is shown to shut down this deleterious pathway, enabling facile arylation of a highly medicinally relevant group of compounds.

    • Vinod G. Landge
    • Michael C. Young
    News & Views
    Nature Chemistry
    Volume: 12, P: 12-14