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Showing 1–7 of 7 results
Advanced filters: Author: Yang-Rong Yao Clear advanced filters
  • Although transition metal-based complexes featuring metal atoms in formally negative oxidation states are known, their stabilization without an organic ligand remains challenging. Now, lanthanide–nickel intermetallic complexes featuring an organic-ligand-free Ni2− ion bound to electropositive lanthanides have been stabilized in fullerenes.

    • Panfeng Chuai
    • Ziqi Hu
    • Zujin Shi
    Research
    Nature Chemistry
    Volume: 17, P: 1053-1057
  • [6,6]-Phenyl-C61-butyric acid methyl ester (PCBM), a star molecule in the fullerene field, has found wide applications in materials science. Here, the authors demonstrate the synthesis of buckyballs with fused-ring systems via electrosynthesis through radical α-C−H functionalization of the side-chain ester for both PCBM and its analogue.

    • Wei-Feng Wang
    • Kai-Qing Liu
    • Guan-Wu Wang
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-8
  • Single-molecule electronics provide the potential solution for high-density integration and low-power consumption in massive data-driven applications, but have yet to be explored. Here, the authors report low-power logic-in-memory operations, based on single electric dipole flipping in the two-terminal single-metallofullerene device at room temperature.

    • Jing Li
    • Songjun Hou
    • Wenjing Hong
    Research
    Nature Materials
    Volume: 21, P: 917-923
  • Diatomic actinide molecules are ideal models for studying rare multiple-bond motifs. Here, the authors report host-guest structures of metastable charged U≡N diatoms confined in fullerene cages and stabilized by coordinative electron transfer.

    • Qingyu Meng
    • Laura Abella
    • Ning Chen
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-10
  • Studying the nature of actinide-actinide bonds is important for understanding the electronic structure of the 5f elements, but the synthesis of these chemical bonds remains extremely challenging. Here, the authors report a strong covalent Th-Th bond formed between two rarely accessible Th3+ ions, stabilized inside a fullerene cage.

    • Jiaxin Zhuang
    • Roser Morales-Martínez
    • Ning Chen
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-8
  • The structures of fullerenes, or buckyballs, are often very difficult to resolve. Here, the authors describe a decapyrrylcorannulene host with ten flexible pyrryl groups that can efficiently co-crystallize with diverse fullerene derivatives in a ‘hand-ball-hand’ fashion, allowing crystallographic identification of commonly known types of fullerenes.

    • Yun-Yan Xu
    • Han-Rui Tian
    • Lan-Sun Zheng
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-9