Migratory alkene isomerizations and cross-coupling reactions are both possible under nickel catalysis, but usually require different conditions. Here the authors show a combined protocol to isomerize a double bond and then, via an in-situ exchange of ligands, perform an enantioselective C(sp2)–C(sp3) cross-coupling.
- Yuli He
- Jiawei Ma
- Shaolin Zhu
