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Advanced filters: Author: Zhan-Lin Wang Clear advanced filters

  • Polar and steric effects usually dictate the regioselectivity in homolytic aromatic substitution. Now a method for direct ortho-selective C–H amination of aromatics with diverse side chains as directing groups is disclosed, by which the iron catalyst coordinates both the substrate and the aminyl radical.

    • Chao-Rui Ma
    • Guan-Wang Huang
    • Fei Wang
    Research
    Nature Catalysis
    Volume: 7, P: 636-645