Semicrystalline polymers are formed when polymer chains have sufficient stereo- and regioregularity, but some unusual atactic polymers can also crystallize despite their lack of regularity, resulting in semicrystalline materials. This Review highlights the factors that induce crystallization in atactic polymers and describes tools for synthesizing them.
- Leire Sangroniz
- Ainara Sangroniz
- Alejandro J. Müller
