Compound 3
Bis-(μ-acetato-O:O')-bis-[benzo[h]quinolinyl-N]-bis-fluorodipalladium
From: Synthesis and structure of solution-stable one-dimensional palladium wires
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InChIKey YFQSVMSIXAMMOA-UHFFFAOYSA-J
Compound data: CIF
Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.
All manipulations were carried out in a dry box under a N2 atmosphere. At −50 °C, a solution of approximately 20 mg of Pd(III) fluoride wire 5 in 1.0 mL CH2Cl2 was was filtered through glass wool into two 2.0 mL plastic vials. Pre-cooled pentane (−50 °C) was carefully layered on top of the solution containing 5. After 24 hours, crystals were observed with two morphologies: red needle crystals that corresponded to Pd(III) wire 5, and red plate crystals that corresponded to the Pd(III) difluoride 3. Redissolved crystals of both 5 and 3 displayed solution state spectral data that is consistent with the presence of 5, rather than 3, in solution.
