Table 2 Compositions for phases in experimental runs AR2 and MR2

From: Assessment of process variability and color in synthesized and ancient Egyptian blue pigments

 

AR2

MR2

 

glass

 

Cuv

 

silica

Wo

 

glass

 

Cuv

 

silica

Wo

 
 

mean

σ

mean

σ

mean

mean

σ

mean

σ

mean

σ

mean

mean

σ

Mass (%) oxide

n = 17

 

n = 5

 

n = 2

n = 3

 

n = 20

 

n = 5

 

n = 2

n = 3

 

SiO2

60.7

0.4

63.5

0.8

97.65

53.6

0.6

61.7

2.1

61.9

0.6

96.07

52.6

0.3

Al2O3

1.43

0.17

0.16

0.13

0.33

0.3

0.03

0.6

0.15

0.19

0.03

0.38

  

Fe2O3

0.40

0.04

     

0.1

0.06

     

MgO

       

0.2

0.06

     

CaO

7.5

1.0

14.48

0.26

0.05

43.3

1.1

2.2

0.7

13.97

0.10

0.15

46.6

0.3

Na2O

8.6

0.4

   

0.5

0.1

14.6

0.5

  

0.31

  

K2O

0.30

0.01

     

0.2

0.18

     

P2O5

       

0.2

0.2

     

CuO

21.1

0.7

21.3

0.1

0.73

1.7

0.04

20.4

1.6

21.2

0.4

0.96

1.5

0.04

Total

100.07

 

99.47

 

98.75

99.4

 

100.3

 

97.30

 

97.86

100.6

 

Cations on the basis of X oxygens

X

10

 

10

  

3

 

10

 

10

  

3

 

Si

3.869

 

3.997

  

1.035

 

3.924

 

3.991

  

1.010

 

Al

0.108

 

0.012

  

0.007

 

0.045

 

0.015

    

Fe

0.008

      

0.002

      

Mg

       

0.015

      

Ca

0.512

 

0.976

  

0.895

 

0.153

 

0.964

  

0.958

 

Na

1.063

    

0.010

 

1.802

      

K

0.024

      

0.018

      

P

       

0.009

      

Cu

1.016

 

1.012

  

0.025

 

0.983

 

1.031

  

0.021

 

Total

6.599

 

5.997

  

1.971

 

6.952

 

6.001

  

1.990

 
  1. Obtained by point analysis of chemical phases within polished cross sections expressed as mass% of oxides and associated cation stoichiometry, (uncertainties represent the 1 sigma level).
  2. Cuv cuprorivaite, Wo wollastonite, X number of oxygens.