Fig. 5: Effect of olefin geometry and synthetic application.

a Effect of allylic benzoates geometry. b 1 mmol scale reaction with reduced catalyst loading. c Ni-catalyzed reduction of γ-chiral amides to δ-chiral amines.
a Effect of allylic benzoates geometry. b 1 mmol scale reaction with reduced catalyst loading. c Ni-catalyzed reduction of γ-chiral amides to δ-chiral amines.