Fig. 1: Nucleophilic ring opening of 3-membered phosphorus heterocycles. | Nature Communications

Fig. 1: Nucleophilic ring opening of 3-membered phosphorus heterocycles.

From: Unlocking the C-centered ring-opening of phosphiranium ions for a straightforward entry to functionalized phosphines

Fig. 1

a General statements: 3-membered phosphorus heterocycles ring-opening; b Electrophilic phosphonium cations (EPC) as source of inspiration; c Representative examples of polyluorinated organocatalysts refs. 36,37,38; d This work: Ring-opening of Electrophilic Phosphiranium Cations (EPrS) with weak protic nucleophiles.

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