Fig. 3: Scope of alkane substrates.

^aReaction conditions: alkyne (0.3 mmol), alkane (10 equiv., 1 atm for gaseous alkane), FeCl₃ (0.001 equiv.), FeCl₂•4H₂O (0.5 equiv.), L6 (0.5 equiv.), and CH₃CN (3 mL) under N₂ and irradiation of a 30 W 365 nm LED for 48 h. ^bFeCl₃ (0.1 equiv).