Fig. 4: Late-stage functionalization.

aReaction conditions: alkyne (0.3 mmol), cyclohexane (10 equiv.), FeCl3 (0.1 equiv.), FeCl2•4H2O (0.5 equiv.), L6 (0.5 equiv.), and CH3CN (3 mL) under N2 and irradiation of a 30 W 365 nm LED for 48 h.
aReaction conditions: alkyne (0.3 mmol), cyclohexane (10 equiv.), FeCl3 (0.1 equiv.), FeCl2•4H2O (0.5 equiv.), L6 (0.5 equiv.), and CH3CN (3 mL) under N2 and irradiation of a 30 W 365 nm LED for 48 h.