Fig. 8: Applications. | Nature Communications

Fig. 8: Applications.

From: Carbon-silicon-switch effect in enantioselective construction of silicon-stereogenic center from silacyclohexadienones

Fig. 8

a–d Synthetic applications. e Pictures of the solution of 15 in UV cuvette under room light, under UV (365 nm) light, and solid under UV (365 nm) light. f UV-vis spectrum of 15 in CH2Cl2 (solid line, 50 µM), fluorescence spectra of 15 in CH2Cl2 (5.0 µM), and solid-state (λex = 410 nm). g Cyclic voltammograms of 15 (1 mM in CH2Cl2, 0.1 M n-Bu4NPF6, 100 mV/s). h CD (circular dichroism) spectra of 15 in CH2Cl2 (3.0 µM). i gabs spectra of 15. cod = 1,5-cyclooctadiene. Py = pyridine.

Back to article page