Fig. 6: Substrate scopes and flow small-scale up. | Nature Communications

Fig. 6: Substrate scopes and flow small-scale up.

From: Synergistic enhancement of electrochemical alcohol oxidation by combining NiV-layered double hydroxide with an aminoxyl radical

Fig. 6

Substrate scopes of the Ni0.67V0.33-LDH, ACT, and Ni0.67V0.33-LDH/ACT-catalyzed EAOa (A) and flow small-scale up (B). a Anode potential and charge passed for Ni0.67V0.33-LDH/ACT-catalyzed EAO in a small-scale flow electrolyzer. b The relative concentration for the Ni0.67V0.33-LDH/ACT-catalyzed EAO of 9a in a small-scale flow electrolyzer. aReaction conditions: Ni0.67V0.33-LDH anode, nickel foam cathode, electrode surface (10 cm2), constant potential = 1.45 V vs. RHE, flow rate = 200 mL min−1, room temperature, 1a-8a (10 mmol), ACT (5 mol%), 0.5 M Na2CO3, MeCN. Small-scale up: electrode surface (100 cm2), apparent current density = 150 mA cm−2, flow rate = 2000 mL min−1, 9a (50 mmol), ACT (5 mol%). Determined by GC-MS and HPLC analysis. Yield of isolated products.

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