Fig. 1: State-of-Art on catalytic asymmetric construction of silicon-stereogenic vinylsilanes and our study.
From: Enantioselective construction of silicon-stereogenic vinylsilanes from simple alkenes

A Asymmetric construction of Si-stereogenic vinylsilanes from alkynes. B Desymmetrizing protoboration of divinyl-substituted silanes (Xiong & Zhang’s work). C Enantioselective 1,5-migration/carbene coupling reaction toward highly enantioenriched silicon-stereogenic vinyl silane. D Asymmetric construction of Si-stereogenic vinylsilanes from simple alkenes (This work).