Fig. 5: Synthetic utility of our product 3aa and development of chiral π-conjugated double bond systems.
From: Enantioselective construction of silicon-stereogenic vinylsilanes from simple alkenes
a the diverse down-stream transformations of product 3aa. (b) the synthesis of chiral π-conjugated double bond systems 17, 18, 19 and 20 bearing quaternary silicon stereocenters. c the images of 17, 18, 19 and 20 in both solution and solid state. d the fluorescence emission spectra of 17, 18, 19 and 20 in DCM and solid state. e CD spectra of 17, 19 and 20 and their enantiomers in CHCl3 (1.0 × 10−4 M) at room temperature.
