Fig. 6: Mechanistic studies.
From: Enantioselective construction of silicon-stereogenic vinylsilanes from simple alkenes
a the preparation of L26-Rh-H catalyst. b the reaction of styrene 1a and SCB 2a by using L26-Rh-H as the catalyst. c the deuterated experiments. d the study of nonlinear effect. e DFT calculation of reaction mechanism. f The optimized geometries of both (S)-TS1 and (R)-TS1.
