Fig. 2: [Cp*Ru(MeCN)3]PF6-catalyzed anti-hydrosilylation.
From: Harnessing the β-boron effect for regioselective Ru-catalyzed hydrosilylation of internal alkynes
Reaction conditions: propargylic B(MIDA) (0.1 mmol, 1.0 equiv.), silane (0.2 mmol, 2.0 equiv.), [Cp*Ru(MeCN)3]PF6 (5 mol%), in 1,4-dioxane or THF (1.0 mL), room temperature.
