Fig. 1: Deaminative functionalization of primary amine.
From: Catalytic diazene synthesis from sterically hindered amines for deaminative functionalization
a Utility of primary amine for conventional nucleophilic amination and deaminative functionalization. b State-of-the-art deaminative functionalization of primary amine. c Multi-step diazene synthesis for deaminative functionalization via sulfonamide. d Multi-step diazene synthesis for deaminative functionalization using hydroxylamine derivatives. e This work: catalytic synthesis of diazenes from α-tertiary amines for deaminative functionalization.
