Fig. 3: Substrate Scope of Sulfenamides.
From: Catalytic synthesis of chiral sulfinimidate esters via oxidative esterification of sulfenamides
Unless otherwise noted, the reaction was performed with sulfenamide 2 (0.10 mmol), 3a (0.20 mmol. 2.0 equiv), Λ-(S,S)−1a (0.01 mmol, 10 mol%), NIS (0.2 mmol, 2.0 equiv), and THF (1.0 mL) at –40 °C for 36 h. Isolated yields are reported, and er values were determined by chiral stationary HPLC. aDCM was used instead of THF (For details, see Table S8 in SI).
