Fig. 2: Reaction scope of hydrosilanes. | Nature Communications

Fig. 2: Reaction scope of hydrosilanes.

From: Catalytic aromatic C−H borylation via strained Si and Ge metallacycles

Fig. 2

Reaction conditions: [Ir(cod)OMe]2 (2.5 mol%), L4 (5.0 mol%), 1 (0.50 mmol), HBpin (1.25 mmol), KOAc (1.25 mmol) in 1.5 mL of THF at 125 °C for 6 h under argon; For entries 8–25: [Ir(cod)OMe]2 (5.0 mol%), L4 (10.0 mol%), HBpin (0.15 mmol), B2pin2 (0.75 mmol), NaOAc (1.25 mmol) at 150 °C. aIsolated yield.

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